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In which one of the following species is the central atom (the first atom in the formula) an exception to the octet rule?


A) NH 3
B) NH 4 +
C) I 2
D) BH 4
E) SF 6

F) B) and D)
G) A) and C)

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Select the best Lewis structure for P2I4.


A) Select the best Lewis structure for P<sub>2</sub>I<sub>4</sub>. A)    B)    C)    D)    E) None of these choices are correct.
B) Select the best Lewis structure for P<sub>2</sub>I<sub>4</sub>. A)    B)    C)    D)    E) None of these choices are correct.
C) Select the best Lewis structure for P<sub>2</sub>I<sub>4</sub>. A)    B)    C)    D)    E) None of these choices are correct.
D) Select the best Lewis structure for P<sub>2</sub>I<sub>4</sub>. A)    B)    C)    D)    E) None of these choices are correct.
E) None of these choices are correct.

F) A) and B)
G) D) and E)

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Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI3 that minimizes formal charges.


A) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> that minimizes formal charges. A)    B)    C)    D)    E)
B) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> that minimizes formal charges. A)    B)    C)    D)    E)
C) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> that minimizes formal charges. A)    B)    C)    D)    E)
D) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> that minimizes formal charges. A)    B)    C)    D)    E)
E) Phosphoryl iodide is used in the preparation of organophosphorus derivatives and phosphate esters. Select the Lewis structure for POI<sub>3</sub> that minimizes formal charges. A)    B)    C)    D)    E)

F) A) and E)
G) A) and C)

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C

Boron never achieves an octet in any of its compounds.

A) True
B) False

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How many resonance structures are possible for NO3?


A) 1
B) 2
C) 3
D) 4
E) 5

F) B) and D)
G) B) and C)

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Which one of the following molecules does not have a dipole moment?


A) CS 2
B) H 2S
C) CH 2Cl 2
D) PH 3
E) CH 2O

F) All of the above
G) B) and C)

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In order for a noncyclic triatomic molecule to be bent, VSEPR theory requires that there must be two lone pairs on the central atom.

A) True
B) False

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Predict the ideal bond angles in GeCl4 using the molecular shape given by the VSEPR theory.


A) 90°
B) 109°
C) 120°
D) 180°
E) < 90°

F) D) and E)
G) C) and D)

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Select the correct Lewis structure for NOCl, a reactive material used as an ionizing solvent.


A) Select the correct Lewis structure for NOCl, a reactive material used as an ionizing solvent. A)    B)    C)    D)    E) None of these choices are correct.
B) Select the correct Lewis structure for NOCl, a reactive material used as an ionizing solvent. A)    B)    C)    D)    E) None of these choices are correct.
C) Select the correct Lewis structure for NOCl, a reactive material used as an ionizing solvent. A)    B)    C)    D)    E) None of these choices are correct.
D) Select the correct Lewis structure for NOCl, a reactive material used as an ionizing solvent. A)    B)    C)    D)    E) None of these choices are correct.
E) None of these choices are correct.

F) B) and E)
G) A) and B)

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In the following Lewis structure for phosphate, phosphorus has a formal charge of __________ and an oxidation number of __________. In the following Lewis structure for phosphate, phosphorus has a formal charge of __________ and an oxidation number of __________.   A) 0; −3 B) 0; 5 C) 5; −3 D) 5; 5 E) 3; 5


A) 0; −3
B) 0; 5
C) 5; −3
D) 5; 5
E) 3; 5

F) A) and E)
G) C) and E)

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Which one of the following molecules has a zero dipole moment?


A) SO 2
B) HCl
C) CS 2
D) CO
E) Cl 2O

F) All of the above
G) B) and E)

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C

Which of the following molecules has a net dipole moment?


A) BeCl 2
B) SF 2
C) KrF 2
D) CO 2
E) CCl 4

F) A) and B)
G) B) and E)

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What is the molecular shape of NH2Cl as predicted by the VSEPR theory?


A) Trigonal pyramidal
B) Tetrahedral
C) T-shaped
D) See-saw
E) Trigonal planar

F) B) and C)
G) A) and E)

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The molecule AX2, where A and X are different elements, will have a dipole moment if the molecule is bent.

A) True
B) False

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All possible resonance structures contribute equally to the resonance hybrid.

A) True
B) False

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The Lewis structure of NO2 violates the octet rule.

A) True
B) False

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When resonance occurs, the bond lengths in a molecule fluctuate rapidly.

A) True
B) False

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Which one of the following molecules contains a double bond?


A) N 2
B) PCl 5
C) CH 2O
D) C 2H 2
E) I 2

F) A) and B)
G) A) and C)

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Select the Lewis structure for XeO2F2 that correctly minimizes formal charges.


A) Select the Lewis structure for XeO<sub>2</sub>F<sub>2 </sub>that correctly minimizes formal charges. A)    B)    C)    D)    E)
B) Select the Lewis structure for XeO<sub>2</sub>F<sub>2 </sub>that correctly minimizes formal charges. A)    B)    C)    D)    E)
C) Select the Lewis structure for XeO<sub>2</sub>F<sub>2 </sub>that correctly minimizes formal charges. A)    B)    C)    D)    E)
D) Select the Lewis structure for XeO<sub>2</sub>F<sub>2 </sub>that correctly minimizes formal charges. A)    B)    C)    D)    E)
E) Select the Lewis structure for XeO<sub>2</sub>F<sub>2 </sub>that correctly minimizes formal charges. A)    B)    C)    D)    E)

F) A) and B)
G) C) and D)

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In the following Lewis structure for ClO3F, chlorine has a formal charge of __________ and an oxidation number of __________. In the following Lewis structure for ClO<sub>3</sub>F, chlorine has a formal charge of __________ and an oxidation number of __________.   A) 7; 7 B) 7; −1 C) 1; 1 D) 1; −1 E) 1; 7


A) 7; 7
B) 7; −1
C) 1; 1
D) 1; −1
E) 1; 7

F) A) and C)
G) A) and B)

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E

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