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In which pair of aldohexoses do the monosaccharides differ from each other by the position of a single hydroxyl group?


A) D-allose and D-altrose
B) D-altrose and D-glucose
C) D-allose and D-mannose
D) D-mannose and D-idose

E) A) and D)
F) C) and D)

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Who proposed the ring or cyclic structures of monosaccharides?


A) E. Fischer
B) W. Haworth
C) L. Pauling
D) L. Pasteur

E) B) and C)
F) A) and D)

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Which carbon atom becomes an anomeric carbon when ribose adopts a furanose structure?


A) carbon 1
B) carbon 2
C) carbon 5
D) carbon 6

E) A) and B)
F) A) and C)

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Which carbon is the site of reaction when glucose reacts with an alcohol to form a glycoside?


A) carbon 1
B) carbon 2
C) carbon 5
D) carbon 6

E) All of the above
F) B) and C)

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In the cyclic structure of fructose, which carbon atoms are connected to the oxygen atom of the furanose ring?


A) carbon 1 and carbon 5
B) carbon 1 and carbon 6
C) carbon 2 and carbon 5
D) carbon 2 and carbon 6

E) All of the above
F) C) and D)

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What is an anomeric carbon?


A) the acetal carbon of the cyclic form of a monosaccharide
B) the hemiacetal carbon of the cyclic form of a monosaccharide
C) the acetal carbon of the cyclic form of a disaccharide
D) the hemiacetal carbon of the cyclic form of a disaccharide

E) C) and D)
F) All of the above

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Identify a membrane-bound carbohydrate that functions as a biochemical marker in animals.


A) D-idose
B) L-fucose
C) D-psicose
D) L-glucose

E) B) and D)
F) B) and C)

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Which statement is true of a solution containing an equilibrium mixture of α-D-glucose and β-D-glucose?


A) The solution contains a larger percentage of the β anomer than the α anomer.
B) The solution does not show optical activity.
C) Both of these statements are correct.
D) Neither of these statements is correct.

E) C) and D)
F) B) and D)

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Which of the following polysaccharides is structurally similar to glycogen?


A) amylopectin
B) amylose
C) cellulose
D) none of these

E) B) and C)
F) All of the above

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To which of the following does galactosemia belong?


A) bacterial diseases
B) viral diseases
C) genetic disorders
D) lifestyle disorders

E) B) and C)
F) All of the above

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Which of the following polysaccharides has only α-1,4-glycosidic bonds?


A) cellulose
B) amylose
C) glycogen
D) none of these

E) A) and B)
F) A) and C)

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How many chiral carbons are present in the open-chain form of a ketohexose?


A) three
B) four
C) five
D) six

E) B) and C)
F) A) and C)

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Which of the following membrane-bound carbohydrates is found in the A antigens of type A blood?


A) N-acetyl-D-galactosamine
B) D-galactose
C) Both N-acetyl-D-galactosamine and D-galactose
D) Neither N-acetyl-D-galactosamine nor D-galactose

E) A) and B)
F) None of the above

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Which of the following is the Fischer projection of D-glyceraldehyde?


A) Which of the following is the Fischer projection of D-glyceraldehyde? A)    B)    C)    D)
B) Which of the following is the Fischer projection of D-glyceraldehyde? A)    B)    C)    D)
C) Which of the following is the Fischer projection of D-glyceraldehyde? A)    B)    C)    D)
D) Which of the following is the Fischer projection of D-glyceraldehyde? A)    B)    C)    D)

E) A) and B)
F) B) and D)

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A

Which of the following is the Fischer projection of L-glyceraldehyde?


A) Which of the following is the Fischer projection of L-glyceraldehyde? A)    B)    C)    D)
B) Which of the following is the Fischer projection of L-glyceraldehyde? A)    B)    C)    D)
C) Which of the following is the Fischer projection of L-glyceraldehyde? A)    B)    C)    D)
D) Which of the following is the Fischer projection of L-glyceraldehyde? A)    B)    C)    D)

E) All of the above
F) C) and D)

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B

What is the physiological role of the enzyme whose deficiency causes galactosemia?


A) It converts D-galactose to lactose.
B) It converts D-galactose to fructose.
C) It converts D-galactose to glucose.
D) It converts D-galactose to sucrose.

E) A) and B)
F) A) and C)

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In the cyclic structure of glucose, which carbon atoms are connected to the oxygen atom of the pyranose ring?


A) carbon 1 and carbon 5
B) carbon 1 and carbon 6
C) carbon 2 and carbon 5
D) carbon 2 and carbon 6

E) All of the above
F) A) and B)

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How does heparin prevent the coagulation of blood?


A) It enhances the production of platelets.
B) Its basic nature helps denature the proteins in blood clots.
C) It binds to antithrombin III, a protein involved in terminating blood clotting.
D) It decreases the production of red blood cells in the body.

E) All of the above
F) B) and D)

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How many monosaccharide units are present in an oligosaccharide?


A) between 3 and 5
B) between 6 and 10
C) between 11 and 15
D) between 15 and 20

E) All of the above
F) B) and C)

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Which of the following statements explains the reducing nature of 2-ketoses?


A) Under acidic conditions, they exist in equilibrium with enediols that get reduced by the reducing agent.
B) Under basic conditions, they exist in equilibrium with aldoses that are oxidized by the oxidizing agent.
C) Both of these statements explain the reducing nature of 2-ketoses.
D) Neither of these statements explains the reducing nature of 2-ketoses.

E) A) and B)
F) A) and C)

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B

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