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What is the mole fraction of water for a mixture prepared by mixing 50.0 grams of glycerol (non-volatile solute) and 500 grams of H2O? Molar Mass(glycerol) = 92.09 g/mol and Molar Mass(H2O) = 18.02 g/mol


A) c water = 0.0192
B) c water = 0.0361
C) c water = 0.0909
D) c water = 0.909
E) c water = 0.981

F) A) and E)
G) B) and E)

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Pepsin is an enzyme present in the human digestive tract. A 30.0 mL solution containing 0.500 grams of pepsin exhibits an osmotic pressure of 8.92 torr at 27.0 ° C. What is the molar mass of pepsin?


A) 35.0 g/mol
B) 46.0 g/mol
C) 3.15×103 g/mol
D) 3.50×104 g/mol
E) 3.54×106g/mol

F) A) and D)
G) A) and E)

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Which of the following would be least soluble in water?


A) Which of the following would be least soluble in water? A)    (acetone)  B)  H<sub>3</sub>C - CH<sub>2</sub> - NH<sub>2</sub> C)  H<sub>3</sub>C - CH<sub>2</sub> - CH<sub>2</sub> - CH<sub>3</sub> D)  H<sub>3</sub>C - CH<sub>2</sub> - OH E)  all are insoluble (acetone)
B) H3C - CH2 - NH2
C) H3C - CH2 - CH2 - CH3
D) H3C - CH2 - OH
E) all are insoluble

F) B) and E)
G) B) and D)

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Ethylene glycol is mixed with water and added to an automobile's radiator. Which of the following occurs? I. The freezing temperature of the mixture rises. II. The vapor pressure inside the radiator increases. III. The boiling temperature of the mixture rises.


A) I only
B) II only
C) III only
D) I and II
E) All of these

F) A) and C)
G) A) and B)

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Lauryl alcohol is obtained from coconut oil and found in many hair shampoos. A solution of 5.00 g of lauryl alcohol in 100.0 g of benzene boils at 80.78 ° C. What is the molar mass of lauryl alcohol if kb = 2.53 ° C/m and the normal boiling point of benzene is 80.10 ° C?


A) 1.3×102 g/mol
B) 1.6×102 g/mol
C) 1.9×102 g/mol
D) 2.5×102 g/mol
E) 46 g/mol

F) C) and D)
G) A) and B)

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Commercial concentrated ammonium hydroxide is 28.0% (m/m) NH3 and has a density of 0.890 g/mL. What is the molarity of a concentrated solution of ammonium hydroxide? MW(NH3) = 17.03 g/mol


A) 5.4 M
B) 14.6 M
C) 16.4 M
D) 18.5 M
E) 22.8 M

F) C) and D)
G) None of the above

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The average osmotic pressure of blood is 7.70 atm at 25 ° C. What is the molar concentration of an aqueous glucose (C6H12O6) solution that is isotonic (equal in concentration) with blood?


A) 2.12×10 - 3 M
B) 0.128 M
C) 0.315 M
D) 1.53 M
E) 3.75 M

F) A) and B)
G) None of the above

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Generally a process is considered favorably spontaneous if the process releases heat to the surroundings. The following three processes are necessary to dissolve a solute such as NaCl in a solvent such as water. Which of these is considered an exothermic process? I. Solute-Solute interactions must be broken. II. Solvent-Solvent interactions must be broken. III. Solute-Solvent interactions are formed.


A) I only
B) II only
C) III only
D) I and II
E) All of these

F) B) and E)
G) None of the above

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What is the mole fraction of glucose in a solution prepared by dissolving 9.01 grams of glucose, C6H12O6, in 17.1 grams of water? Molar Mass(C6H12O6) = 180.16 g/mol and Molar Mass(H2O) = 18.02 g/mol


A) c glucose = 0.0503
B) c glucose = 0.345
C) c glucose = 0.527
D) c glucose = 0.909
E) c glucose = 0.950

F) A) and B)
G) None of the above

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The mole fraction of acetone in a solution prepared by mixing 58.1 g acetone (C3H6O) and 72.1 g of H2O is:


A) 0.200
B) 0.250
C) 0.446
D) 0.806
E) 1.00

F) C) and E)
G) A) and D)

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How many grams of Na2SO4 are required to make 43.5 mL of a 13.7% (m/v) aqueous solution?


A) 0.168 g Na2SO4
B) 5.96 g Na2SO4
C) 13.7 g Na2SO4
D) 31.5 g Na2SO4
E) 318 g Na2SO4

F) B) and E)
G) A) and D)

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The density of a solution that is 18.0% by mass lead nitrate [Pb(NO3) 2] is 1.18 g/cm3. Calculate the molarity of the lead nitrate solution.


A) 4.9×10 - 7 M
B) 0.64 M
C) 12.0 M
D) 19.8 M
E) 15.3 M

F) A) and C)
G) B) and D)

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Calculate the osmotic pressure at 310 K of a sugar solution containing 42.0 g of sucrose (C12H22O11) in 650 mL of solution.


A) 3.12 atm
B) 0.065 atm
C) 1.64 atm
D) 1069 atm
E) 4.80 atm

F) A) and B)
G) A) and C)

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A 10.0 mass percent solution of a nonelectrolyte dissolved in carbon tetrachloride has a boiling point that is 4.50 ° C higher than the solvent. What is the molar mass of this solute given kb is 5.03 ° C/m?


A) 112 g/mol
B) 124 g/mol
C) 150 g/mol
D) 11.2 g/mol
E) none of these

F) C) and D)
G) A) and D)

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A solution of ethanol (C2H5OH) in water is 15.0% ethanol by weight. The molality of this solution is:


A) 15.0 m
B) 3.83 m
C) 3.25 m
D) 1.77 m
E) none of these

F) B) and D)
G) B) and C)

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In a study designed to prepare new gasoline-resistant coating, a polymer chemist dissolves 6.061 g poly(vinyl alcohol) in enough water to make 100.0 mL of solution. At 25 ° C, the osmotic pressure of this solution is 0.248 atm. What is the molar mass of the polymer sample?


A) 0.0101 g/mol
B) 73.2 g/mol
C) 502 g/mol
D) 5.98×103 g/mol
E) 8.87×105 g/mol

F) B) and D)
G) All of the above

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What type of solute-solvent interaction is most important in a solution that contains Na2SO4 dissolved in water?


A) Dipole-Dipole
B) Ion-Dipole
C) Hydrogen bonding interactions
D) London dispersion-London dispersion interactions
E) London dispersion-Dipole interactions

F) A) and C)
G) All of the above

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The concentration of O2 (g) dissolved in water that is saturated with air (20 mole % O2) is 2.86×10 - 4 molal. What is the Henry's law constant for this gas, in molal/atm?


A) 1.43×10 - 3
B) 2.86×10 - 4
C) 5.72×10 - 5
D) 8.01×10 - 3
E) none of these

F) B) and D)
G) All of the above

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How many moles of solute are present in 50.0 grams of solution that is 2.50% by mass glucose (C6H12O6) ? MM(C6H12O6) = 180.16 g/mol


A) 6.94×10 - 3 moles
B) 0.800 moles
C) 1.25 moles
D) 11.1 moles
E) 225 moles

F) A) and D)
G) All of the above

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Which of the following colligative properties is the most sensitive to change in concentration?


A) vapor pressure of solvent
B) freezing point
C) boiling point
D) osmotic pressure
E) all are about equally sensitive

F) None of the above
G) A) and E)

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