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A solution that contains 2.00 g of ferrocene [molar mass = 186.0 g/mol] dissolved in 50.0 g of ethylene bromide (C2H4Br2) has a freezing point of 7.26 ° C. The normal freezing point of ethylene bromide is 9.80 ° C. What is the freezing point depression constant for this solvent?


A) 11.8 ° C/m
B) 1.86 ° C/m
C) 4.90 ° C/m
D) 63.5 ° C/m
E) none of these

F) None of the above
G) C) and D)

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What is the mass percent , %(m/m) , of an aqueous solution prepared by dissolving 12.5 g of KNO3 in 125 g of water?


A) 0.0909%
B) 0.100%
C) 9.09%
D) 10.0%
E) 90.9%

F) B) and C)
G) C) and D)

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What is the molality of a solution prepared by mixing 22 g of ethylene glycol (molar mass = 62 g/mol) with 108 g of water?


A) 0.17 m
B) 0.20 m
C) 3.3 m
D) 12. m
E) none of these

F) B) and E)
G) A) and E)

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Arrange the following solutions in order of increasing boiling point. 0.15 M Li3PO4 0.25 M MgSO4 0.55 M glucose (C6H12O6)


A) (lowest bp) 0.15 M Li3PO4 < 0.25 M MgSO4 < 0.55 M glucose (highest bp)
B) (lowest bp) 0.55 M glucose < 0.25 M MgSO4 < 0.15 M Li3PO4 (highest bp)
C) (lowest bp) 0.15 M Li3PO4 < 0.55 M glucose < 0.25 M MgSO4 (highest bp)
D) (lowest bp) 0.25 M MgSO4 < 0.15 M Li3PO4 < 0.55 M glucose (highest bp)
E) (lowest bp) 0.25 M MgSO4 < 0.55 M glucose < 0.15 M Li3PO4 (highest bp)

F) A) and D)
G) A) and E)

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How many grams of solute are present in 164.1 mL of 0.207 M calcium acetate, Ca(C2H3O2) 2? MM[Ca(C2H3O2) 2] = 158.17 g/mol


A) 0.200 g Ca(C2H3O2) 2
B) 0.215 g Ca(C2H3O2) 2
C) 4.66 g Ca(C2H3O2) 2
D) 5.01 g Ca(C2H3O2) 2
E) 5.37 g Ca(C2H3O2) 2

F) A) and B)
G) D) and E)

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The presence of a nonvolatile solute in water will:


A) lower the freezing point, vapor pressure, and boiling point.
B) raise the freezing point, vapor pressure, and boiling point.
C) lower the freezing point and vapor pressure and raise the boiling point.
D) raise the freezing point and lower the vapor pressure and boiling point.
E) have no effect.

F) C) and D)
G) A) and D)

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How many grams of glucose must be added to 275 g of water in order to prepare a 31.0% aqueous glucose solution?


A) 7.78 g glucose
B) 85.3 g glucose
C) 124 g glucose
D) 612 g glucose
E) 887 g glucose

F) C) and E)
G) C) and D)

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A dilute aqueous solution of an organic compound soluble in water is formed by dissolving 2.18 grams of the compound in water to form 0.250 L of solution. The resulting solution has an osmotic pressure of 0.638 atm at 25 ° C. What is the molar mass of this organic compound?


A) 20.9 g/mol
B) 28.0 g/mol
C) 136 g/mol
D) 334 g/mol
E) 1.26×103 g/mol

F) A) and B)
G) B) and D)

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What is the molarity of ions in an aqueous 0.4 M Al(NO3) 3 solution?


A) 0.1 M
B) 0.4 M
C) 0.8 M
D) 1.6 M
E) 5.2 M

F) C) and D)
G) A) and B)

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How many grams of NaCl must be dissolved in 500 g of H2O to prepare a 0.750 m solution? Molar Mass(NaCl) = 58.44 g/mol


A) 6.42×10 - 3 g NaCl
B) 0.156 g NaCl
C) 21.9 g NaCl
D) 39.0 g NaCl
E) 87.7 g NaCl

F) D) and E)
G) A) and B)

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A solution is prepared by mixing 22 g ethylene glycol [C2H4(OH) 2] with 108 g of water. What is the mass percent of ethylene glycol in the solution?


A) 20%
B) 17%
C) 22%
D) 83%
E) none of these

F) All of the above
G) A) and B)

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Which of the substances listed below is more soluble in hexane (C6H14) than in water?


A) KI
B) C2H5OH
C) C10H21Cl
D) CH3NH2
E) none of these

F) A) and B)
G) A) and E)

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A 3.38 molar solution of cesium chloride (molar mass = 168.4 g/mol) has a density of 1.423 g/mL. What is the molality of the solution?


A) 4.81 m
B) 3.96 m
C) 3.38 m
D) 2.38 m
E) none of these

F) All of the above
G) C) and E)

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How many moles of sucrose, C12H22O11, is present in 80.0 grams of an aqueous solution that is 3.50% sucrose by mass? MM(C12H22O11) = 342.30 g/mol


A) 8.18×10 - 3 moles
B) 0.150 moles
C) 2.80 moles
D) 122 moles
E) 958 moles

F) B) and D)
G) B) and E)

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What is the van't Hoff factor for an aqueous solution of Potassium carbonate?


A) i = 1
B) i = 2
C) i = 3
D) i = 4
E) i = 6

F) B) and C)
G) C) and D)

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Glacial acetic acid, HC2H3O2, is 99.8% (m/m) . What is this solution's Molar concentration if its density is 1.049 g/mL? MM(HC2H3O2) = 60.05 g/mol


A) 1.05 M
B) 6.31 M
C) 15.8 M
D) 16.6 M
E) 17.4 M

F) B) and E)
G) B) and D)

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Calculate the osmotic pressure at 298 K of a solution made by dissolving 0.10 g of CaCl2 in water and diluting to 100 mL.


A) 0.022 atm
B) 0.22 atm
C) 0.66 atm
D) 2.4 atm
E) 1.2 atm

F) A) and B)
G) A) and C)

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Which substance listed below would be most likely to dissolve in H2O?


A) BaCl2
B) I2
C) C2H6
D) CH2Cl2
E) none would dissolve

F) A) and B)
G) A) and E)

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How many grams of H2SO4 are present in 75.0 mL of 12.0 M H2SO4? MM (H2SO4) = 98.09 g/mol


A) 1.63 g H2SO4
B) 9.18 g H2SO4
C) 15.7 g H2SO4
D) 88.3 g H2SO4
E) 613 g H2SO4

F) All of the above
G) C) and E)

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What is the definition for molarity ?


A) Grams of solute per moles of solute
B) Moles of solute per grams of solution
C) Moles of solute per Liter of solvent
D) Grams of solute per Liter of solution
E) Moles of solute per Liter of solution

F) A) and E)
G) C) and D)

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