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Describe how and why formal charges are used to choose between two possible Lewis structures for a molecule.

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Formal charges are used to identify the ...

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Rank the following species in order of decreasing carbon-oxygen bond energy: CO,CO2,CO32-.

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From largest to smal...

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Which of the following requires the smallest energy to separate the ions?


A) CaF2
B) KF
C) NaF
D) MgF2
E) LiF

F) B) and E)
G) A) and E)

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Which of the following molecular ions has 3 valence electrons in its Lewis structure?


A) H2+
B) He2+
C) C2+
D) B2+
E) O2-

F) A) and B)
G) B) and E)

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Which of the following is the longest bond? The number in parentheses is the bond energy.


A) C - C (348 kJ/mol)
B) C - F (453 kJ/mol)
C) C - H (411 kJ/mol)
D) C - Cl (339 kJ/mol)
E) C - O (358 kJ/mol)

F) A) and B)
G) A) and C)

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Nitrite (NO2-) is an important nutrient in the eutrophic zone of the ocean.Which of the following is the best set of resonance structures for this ion? Nitrite (NO<sub>2</sub><sup>-</sup>) is an important nutrient in the eutrophic zone of the ocean.Which of the following is the best set of resonance structures for this ion?   A) a B) b C) c D) d E) none of these


A) a
B) b
C) c
D) d
E) none of these

F) D) and E)
G) A) and E)

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Which of the following statements is false regarding the Lewis structure of trichloroacetic acid,CH2Cl3O2? A partial bonding framework is given. Which of the following statements is false regarding the Lewis structure of trichloroacetic acid,CH<sub>2</sub>Cl<sub>3</sub>O<sub>2</sub>? A partial bonding framework is given.   A) The atom at position  X  is hydrogen. B) In the correct and complete Lewis structure,the atom at position  D  violates the octet rule. C) Another double bond is required in order for all of the atoms to attain full valence shells. D) The oxygen atom shown has two pairs of nonbonding electrons. E) In the correct and complete Lewis structure,all of the chlorine atoms have nonbonding pairs of electrons.


A) The atom at position "X" is hydrogen.
B) In the correct and complete Lewis structure,the atom at position "D" violates the octet rule.
C) Another double bond is required in order for all of the atoms to attain full valence shells.
D) The oxygen atom shown has two pairs of nonbonding electrons.
E) In the correct and complete Lewis structure,all of the chlorine atoms have nonbonding pairs of electrons.

F) A) and B)
G) None of the above

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What is the total number of electrons assigned to the oxygen atom in the Lewis structure of formaldehyde (H2CO) ?


A) 8
B) 6
C) 4
D) 2
E) 10

F) A) and E)
G) A) and C)

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Coulomb's law states that the interaction energy between ions depends __________


A) only on the ionic charges.
B) only on the distance between the ions.
C) directly on both the ionic charges and the distance between the ions.
D) on the temperature.
E) directly on the ionic charges and inversely on the distance between the ions.

F) A) and D)
G) B) and D)

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How many valence electrons are there in a correctly drawn Lewis structure for formamide,HCONH2?


A) 12
B) 14
C) 16
D) 18
E) 20

F) B) and D)
G) C) and D)

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What is the correct name for Mg3(PO4)2?

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Draw the Lewis structure of boron trifluoride.

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Carbonyl fluoride (COF2)is similar in structure to phosgene (COCl2)and both are highly toxic.Draw the Lewis structure of COF2.

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Vinegar is a solution of acetic acid (CH3COOH) and water.Which of the following is the Lewis structure for acetic acid? Vinegar is a solution of acetic acid (CH<sub>3</sub>COOH) and water.Which of the following is the Lewis structure for acetic acid?    A) a B) b C) c D) d E) none of these


A) a
B) b
C) c
D) d
E) none of these

F) All of the above
G) B) and D)

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Which ion cannot be considered to have 8 valence electrons?


A) H-
B) Na+
C) Al3+
D) P3-
E) Ar

F) A) and B)
G) A) and E)

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Aqua regia is a mixture of hydrochloric acid and nitric acid that is capable of dissolving gold.What are the formulas of these acids?


A) HClO,HNO4
B) HClO4,HNO3
C) HCl,HNO2
D) HCl,HNO3
E) HCl,HNO

F) D) and E)
G) All of the above

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Which of the following statements regarding the Lewis structure of atoms and ions is NOT true?


A) Charges on ions must be explicitly shown.
B) A magnesium ion with a +2 charge has no electron dots shown.
C) A neutral oxygen atom has two pairs of electron dots and two unpaired dots shown.
D) The chloride ion with a -1 charge has eight valence electrons dots shown.
E) The sodium ion has eight valence electron dots shown.

F) B) and C)
G) A) and E)

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Which of the following are listed in order of decreasing electronegativity?


A) F > S > Na > H
B) F > N > P > O
C) N > P > Si > S
D) F > S > Se > Sb
E) Te > Se > S > O

F) C) and D)
G) D) and E)

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Which of the following compounds is likely to have the least reactive hydrogen?


A) H - Br (141 pm)
B) H - I (161 pm)
C) H - Cl (127 pm)
D) H - F (92 pm)
E) H - S (in H2S; 134 pm)

F) C) and E)
G) A) and D)

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Which one of the ionic compounds below would you expect to have the largest (most negative) lattice energy?


A) MgO
B) CaO
C) SrO
D) BaO
E) BeO

F) A) and E)
G) B) and D)

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